Well, I could do what you mentioned mysteryman, but as my rings haven't even been around the block following a complete rebuild, I just don't want to chance all that extra oil in a VERY clean top end right now.
But one other thing that would come into play would be that the top piston ring sits a way down the bore from the top surface of the head; this would lead to quite a misleading number I figure. I realise that this is the "actual" cumbustion chamber volume as you were getting at, but why get dirty if someone can give you the numbers while typing at a keyboard!
One other problem is that the only measured tool that I have procured to date, is a 1 cc dropper from the pharmacy. I think it's a diabetic syringe. There would be a whole lot of pumping to do with something that small.
Just as a fun thing, I'm going to check the compression on the cylinders to see if they either stabilize slightly with time (and break-in) and to see if they have been upped slightly as the numbers would indicate.
Thanks for the idea all the same.